potassium thiocyanate signal word

Molecular Weight 97.18 . [citation needed], Phospholipids or some detergents aid the transfer of thiocyanatoiron into chlorinated solvents like chloroform and can be determined in this fashion. When the hands are brought into contact, the solutions react and the effect looks remarkably like stigmata. H302, H312, H332, H400, H410: GHS precautionary statements. Signal Word Warning Hazard Statements H272 - May intensify fire; oxidizer Precautionary Statements P280 - Wear protective gloves/protective clothing/eye protection/face protection P221 - Take any precaution to avoid mixing with combustibles P371 + P380 + P375 - In case of major fire and large quantities: Evacuate area. Signal Word Warning Hazard Statement H332 Harmful if inhaled H312 Harmful in contact with skin H302 Harmful if swallowed H412 Harmful to aquatic life with long-lasting effects Precautionary Statement P273 Avoid release to the environment. [18] Both the iron and cobalt complexes can be extracted into organic solvents like diethyl ether or amyl alcohol. The compound has a low melting point relative to most other inorganic salts. Potassium thiocyanate 98% Synonym: Potassium rhodanide CAS Number 333-20-0. H412-Harmful to aquatic life with long lasting effects. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-10191 Signal Word WARNING SECTION 2 — HAZARDS IDENTIFICATION Hazard class: Skin corrosion or irritation (Category 3). Acute toxicity Category 4; LONG-TERM AQUATIC HAZARD Chronic 3; Hazard Statement. Its crystalline structure has been analyzed based on polarized infrared spectral data. Beilstein/REAXYS Number 3594799 . From Wikipedia, the free encyclopedia Nickel (II) thiocyanate is a coordination polymer with formula Ni (SCN) 2. Ph Eur CAS #: 333-20-0 Molar Mass: 97.18 g/mol Chemical Formula: KSCN Hill Formula: CKNS. It can be painted onto a surface or kept as a colorless solution. Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H302 - Harmful if swallowed H315 - Causes skin irritation H319 - Causes serious eye irritation H402 - Harmful to aquatic life Precautionary statements (GHS-US) : P264 - Wash exposed skin thoroughly after handling. EC Number 206-370-1. Potassium thiocyanate ( kalium tiosianat ) MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. Hazard class: Serious eye damage or irritation (Category 2B). Causes eye irritation … [6][7][8] Thus the complete absence of thiocyanate or reduced thiocyanate[9] in the human body, (e.g., cystic fibrosis) is damaging to the human host defense system. Hazard class: Acute toxicity, oral, dermal, and inhalation (Category 4). Thiocyanate is analogous to the cyanate ion, [OCN]−, wherein oxygen is replaced by sulfur. Lesser amounts of other hydrated compounds also form: e.g. [16], If [SCN]− is added to a solution with iron(III) ions, a blood-red solution forms mainly due to the formation of [Fe(SCN)(H2O)5]2+, i.e. This allows the determination of these ions even in strongly coloured solutions. Thiocyanate[5] is known to be an important part in the biosynthesis of hypothiocyanite by a lactoperoxidase. Several synthesis routes exist, the most basic being the reaction between alkyl halides and alkali thiocyanate in aqueous media. Potassium thiocyanate-13C 99 atom % 13C | Sigma-Aldrich. Download Product Safety Card; … Dilute aqueous KSCN is occasionally used for moderately realistic blood effects in film and theater. Packaging 50, 250 g in poly bottle Safety & Documentation. It is an important salt of the thiocyanate anion, one of the pseudohalides. Thiocyanate (also known as rhodanide) is the anion [SCN] −. SECTION 2 — HAZARDS IDENTIFICATION. The Brief Profile summarizes the non-confidential data on substances as it is held in the databases of the European Chemicals Agency (ECHA), including data provided by third parti Signal Word: Danger: Storage class: 10 - 13 Other liquids and solids: WGK: WGK 1 slightly hazardous to water: Disposal : 3 Relatively unreactive organic reagents should be collected in container A. Aqueous KSCN reacts almost quantitatively with Pb(NO3)2 to give Pb(SCN)2, which has been used to convert acyl chlorides to isothiocyanates. Experimental evidence leads to the general conclusion that class A metals (hard acids) tend to form N-bonded thiocyanate complexes, whereas class B metals (soft acids) tend to form S-bonded thiocyanate complexes. Molecular Weight 97.18 . It facilitates the ring opening of aziridines with high regioselectivity. H412-Harmful to aquatic life with long lasting effects. Thus this chemical is often used to create the effect of 'stigmata'. Potassium thiocyanate is the chemical compound with the molecular formula KSCN. 4 (H312) Acute Tox. Precautionary Statement Signal word Warning Page 1 of 7 Potassium Thiocyanate CAS No 333-20-0 MATERIAL SAFETY DATA SHEET SDS/MSDS. Supplemental … It is the conjugate base of thiocyanic acid. Hazard statement(s ) H302 + H312 + H332 H412 Precautionary statement(s ) P273 P280 Harmful if swallowed, in contact with skin or if inhaled Harmful to aquatic life with long lasting effects. [14] Sodium nitroprusside, a metabolite of which is thiocyanate, is however still used for the treatment of a hypertensive emergency. Signal Word. [10][11], Thiocyanate is a potent competitive inhibitor of the thyroid sodium-iodide symporter. GHS Signal word: Warning: GHS hazard statements. Mercury(II) thiocyanate was formerly used in pyrotechnics. Infobox references: Cobalt(II) thiocyanate … Organic compounds containing the functional group SCN are also called thiocyanates. … Storage: Not applicable. H312-Harmful in contact with skin. EUH032-Contact with acids liberates very toxic gas. Avoid release to the environment. Symbol GHS05,GHS07. what is ?) Signal Word: Not applicable. Common derivatives include the colourless salts potassium thiocyanate and sodium thiocyanate. Rhodanese catalyzes the reaction of sodium nitroprusside with thiosulfate to form the metabolite thiocyanate. Beilstein/REAXYS Number 3594799 . PubChem Substance ID 24898354. As a consequence, thiocyanate can act as a nucleophile at either sulfur or nitrogen — it is an ambidentate ligand. Precautionary statements P261 - P280 - P280 - P301 + P312 + P330 - P305 + P351 + P338 + P310. SDS; CoA; Synonyms: Potassium sulfocyanide EC Number: 206-370-1 Grade: ACS,ISO,Reag. [3] For this purpose, the KSCN is first melted under vacuum to remove water. Signal Word: Warning: Hazard Declaration: H302 + H312 + H332; H412: Symbol: GHS07: Caution Statement: P273; P280: Supplemental Hazard Statements : Contact with acids liberates very toxic gas. GHS Signal word: Warning: GHS hazard statements. Warning; Hazard Category. [SCN]− can also bridge two (M−SCN−M) or even three metals (>SCN− or −SCN<). SECTION 2 — HAZARDS IDENTIFICATION. Organic compounds containing the functional group SCN are also called thiocyanates. Organic and transition metal derivatives of the thiocyanate ion can exist as "linkage isomers". Potassium thiocyanate BioXtra, ≥99.0% Synonym: Potassium rhodanide CAS Number 333-20-0. MSDS: Chinese USA: Flash Point: 500°C: Symbol: GHS07: Signal Word: Warning × [citation needed]. Synthesis Route Total 43 Documents >> 57-06-7. allyl isothiocyanate. If halogenated, they should be collected in container B. … 77, No. [2], KSCN converts ethylene carbonate to ethylenesulfide. Potassium Thiocyanate,ACS Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com SECTION 1 : Identification of the substance/mixture and of the supplier Product name : Potassium Thiocyanate,ACS Manufacturer/Supplier Trade name: Manufacturer/Supplier Article number: S25506A Recommended uses of the product and uses restrictions on use: Manufacturer … EC Number 206-370-1. Precautionary Statement. Potassium Thiocyanate Flinn Scientific, Inc. P.O. Thiocyanate shares its negative charge approximately equally between sulfur and nitrogen. Potassium thiocyanate (KSCN) is a potassium salt of thiocyanate anion. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-10191 Signal Word WARNING. 105125 View Pricing & Availability. Linear Formula KSCN . Do not eat, drink or smoke … Linear Formula KSCN . Potassium thiocyanate MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. Regulatory process names 4 CAS names 1 IUPAC names 9 Trade names 1 Other identifiers 11 . H302, H312, H332, H410: GHS precautionary statements . Use in chemical synthesis Classified: Product: Potassium Thiocyanate Solutions Revision Date: 05/19/2016 1/7 . [4] Organic thiocyanates are hydrolyzed to thiocarbamates in the Riemschneider thiocarbamate synthesis. If halogenated, they should be collected in container B. [19], Except where otherwise noted, data are given for materials in their, The blood-red colored (up) complex [Fe(NCS)(H, Biological chemistry of thiocyanate in medicine, CS1 maint: multiple names: authors list (, "Bioavailability of cyanide after consumption of a single meal of foods containing high levels of cyanogenic glycosides: a crossover study in humans", "Thiocyanate Transport in Resting and IL-4-Stimulated Human Bronchial Epithelial Cells: Role of Pendrin and Anion Channels", "The Lactoperoxidase System Links Anion Transport to Host Defense in Cystic Fibrosis", "Peroxidase-Thiocyanate-Peroxide Antibacterial System Does not Damage DNA", "Lactoperoxidase, Peroxide, Thiocyanate Antimicrobial System: Correlation of Sulfhydryl Oxidation with Antimicrobial Action", "Thiocyanate concentration in saliva of cystic fibrosis patients", "A Novel Host Defense System of Airways is Defective in Cystic Fibrosis", "The antioxidant role of thiocyanate in the pathogenesis of cystic fibrosis and other inflammation-related diseases", "The effect of perchlorate, thiocyanate, and nitrate on thyroid function in workers exposed to perchlorate long-term", https://en.wikipedia.org/w/index.php?title=Thiocyanate&oldid=991810105, Articles with dead external links from June 2018, Articles with permanently dead external links, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Articles with unsourced statements from February 2019, Creative Commons Attribution-ShareAlike License, This page was last edited on 1 December 2020, at 22:58. Sodium thiocyanate may be used as a reducing agent in the preparation of monodisperse gold oligoclusters. H302-Harmful if swallowed. SDS; CoA; Brochures; Synonyms: Potassium sulfocyanide Molar Mass: 97.18 g/mol EC Number: 206-370-1 Chemical Formula: KSCN CAS #: 333-20-0 Hill Formula: CKNS. [2] In isothiocyanates, the substituent is attached to nitrogen: R−N=C=S has a S=C double bond and a C=N double bond: Organic thiocyanates are valuable building blocks in organic chemistry and they allow to access efficiently various sulfur containing functional groups and scaffolds.[3]. AgSCN is monoclinic with 8 molecules per unit cell. Hazard class: Skin corrosion or irritation (Category 3). Signal word Danger. MDL number MFCD00011413. Label elements Signal Word Warning Hazard Statements H412 - Harmful to aquatic life with long lasting effects H302 - Harmful if swallowed H332 - Harmful if inhaled H312 - Harmful in contact with skin EUH032 - Contact with acids liberates very toxic gas Precautionary Statements Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-10190 Signal Word WARNING. Response: Not applicable. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. The compound has a low melting point relative to most other inorganic salts. NACRES NA.31 Signal word (GHS US) : Warning Hazard statements (GHS US) : H272 - May intensify fire; oxidizer H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation Precautionary statements (GHS US) : P210 - Keep away from heat, hot surfaces, open flames, sparks. kinetics and solubility, are sometimes involved, and linkage isomerism can occur, for example [Co(NH3)5(NCS)]Cl2 and [Co(NH3)5(SCN)]Cl2. In the early 20th century, thiocyanate was used in the treatment of hypertension, but it is no longer used because of associated toxicity. [12] Iodine is an essential component of thyroxine. Signal Word Warning Hazard Statements Harmful if swallowed Harmful in contact with skin Harmful if inhaled Company Fisher Scientific One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100 Acute oral toxicity Category 4 Acute dermal toxicity Category 4 Acute Inhalation Toxicity - Dusts and Mists Category 4 _____ Page 1 / 7 _____ Potassium thiocyanate Revision Date 17-Jan-2018 … It is a green-brown solid and its crystal structure was determined first in 1982. Detail>> 420-04-2. cyanamide. Pictograms: Not applicable. 4 (H332) Aquatic Chronic 3 (H412) (EUH032) Xn; R20/21/22 R32 R52-53 For the full text of the R-phrases and H-Statements mentioned in this Section, … Wear protective gloves/ protective clothing. MDL number MFCD00011413 The inhibition efficiency of KSCN dissolved in 1M HCl against the corrosion of carbon-steel has been evaluated. Potassium Thiocyanate, 10% w/v Safety Data Sheet according to Federal Register / Vol. Harmful if swallowed, inhaled or in contact with skin (H302+H312+H332). P273, P280, P501: NFPA 704 (fire diamond) 0. Potassium thiocyanate 333-20-0 EEC No. H332-Harmful if inhaled. It is the conjugate base of thiocyanic acid. Toxicity Statement: Not … Causes mild skin irritation (H316). H312-Harmful in contact with skin. 333-20-0. potassium thiocyanate. P280 Wear protective gloves/protective clothing/ eye protection/face protection. Other factors, e.g. Because both solutions are colorless, they can be placed separately on each hand. Hazard class: Serious eye damage or irritation (Category 2B). Thiocyanate (also known as rhodanide) is the anion [SCN]−. When in contact with ferric chloride solution (or other solutions containing Fe3+), the product of the reaction is a solution with a blood red colour, due to the formation of the thiocyanatoiron complex ion. Supporting you all the way Balance Servicing; Microscope Servicing; Chemical Waste Disposal; Rapid Response Cleaning Potassium Thiocyanate Solution Flinn Scientific, Inc. P.O. Common derivatives include the colourless salts potassium thiocyanate and sodium thiocyanate. Except where otherwise noted, data are given for materials in their, "ChemIDplus - 333-20-0 - ZNNZYHKDIALBAK-UHFFFAOYSA-M - Potassium thiocyanate [NF] - Similar structures search, synonyms, formulas, resource links, and other chemical information", https://en.wikipedia.org/w/index.php?title=Potassium_thiocyanate&oldid=992539059, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Articles with unsourced statements from February 2009, Creative Commons Attribution-ShareAlike License, This page was last edited on 5 December 2020, at 20:15. 490563 Sigma-Aldrich. Infobox references: Structure. In a related reaction, KSCN converts cyclohexene oxide to the corresponding episulfide.[4]. Ion adsorption to aqueous interfaces involving complex organic molecules is relevant to biology in connection with the familiar but incompletely understood Hofmeister effects. Potassium thiocyanate. Hazard Statements: Not applicable. 105124 View Pricing & Availability. Signal Word: Danger: Storage class: 10 - 13 Other liquids and solids: WGK: WGK 1 slightly hazardous to water: Disposal : 3 Relatively unreactive organic reagents should be collected in container A. KSCN is also the starting product for the synthesis of carbonyl sulfide. Safety Information. [17], Similarly, Co2+ gives a blue complex with thiocyanate. pentaaqua(thiocyanato-N)iron(III). Since thiocyanates will decrease iodide transport into the thyroid follicular cell, they will decrease the amount of thyroxine produced by the thyroid gland. Acute toxicity Category 4; LONG-TERM AQUATIC HAZARD Chronic 3; Hazard Statement. Potassium thiocyanate, "ATP1 to CLP" Implementation: EU Remarks: CLP Annex VI table 3.1 (ATP to CLP 790/2009 of 10 August 2009): 615-004-00-3 "salts of thiocyanic acid, with the exception of those specified elsewhere in this Annex". Recent experimental and theoretical results have firmly established the existence of enhanced concentrations of selected ions at the air/water interface. EUH032-Contact with acids liberates very toxic gas. 333-20-0. potassium thiocyanate. 206-370-1 >95 Acute Tox. It is an important salt of the thiocyanate anion, one of the pseudohalides. Diallyl sulfide. Disposal: Not applicable. Hazards Not Otherwise Not applicable. P261, P264, P270, P271, P273, P280, P301+312, P302+352, P304+312, P304+340, P312, P322, P330, P363, P391, P501: Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Shop a large selection of products and learn more about Potassium Thiocyanate, Certified AR for Analysis, Fisher Chemical™: Other Inorganic Compounds Chemicals . - No smoking. Thiocyanate is produced by the reaction of elemental sulfur or thiosulfate with cyanide: The second reaction is catalyzed by thiosulfate sulfurtransferase, a hepatic mitochondrial enzyme, and by other sulfur transferases, which together are responsible for around 80% of cyanide metabolism in the body.[1]. Thiocyanate used to be known as rhodanide (from a Greek word for rose) because of the red colour of its complexes with iron. Download Product Safety Card; Recommended … H332-Harmful if inhaled. Potassium Thiocyanate Solution Flinn Scientific, Inc. P.O. Mercury(II) thiocyanate was formerly used in pyrotechnics. [SCN]− is one of the pseudohalides, due to the similarity of its reactions to that of halide ions. 592-88-1. Precautionary Statements: Prevention: Not applicable. 2. Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Causes mild skin irritation (H316). 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 04/24/2015 Version: 1.0 04/24/2015 EN (English US) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. P270 - Do not eat, drink or smoke when using this product. As such, foodstuffs containing thiocyanate are best avoided by Iodide deficient hypothyroid patients.[13]. H302-Harmful if swallowed. Potassium thiocyanate; Signal Word. 4 (H302) Acute Tox. Potassium thiocyanate CAS Number: 333-20-0: Molecular Weight: 97.181: Density: 1.886: Boiling Point: 500°C: Molecular Formula: CKNS: Melting Point: 173 °C(lit.) Hazard statements H302 + H312 + H332 - H318 - H412. Potassium thiocyanate is the chemical compound with the molecular formula KSCN. Potassium thiocyanate Revision Date 15-Feb-2019 2.2. Fe(SCN)3 and [Fe(SCN)4]−. Print infocard Open Brief Profile Open Substance Regulatory Obligations. 0. Warning; Hazard Category. The determination of Co(II) in the presence of Fe(III) is possible by adding KF to the solution, which forms uncoloured, very stable complexes with Fe(III), which no longer react with SCN−. In thiocyanates, the organic group (or metal ion) is attached to sulfur: R−S−C≡N has a S–C single bond and a C≡N triple bond. Similarly, this reaction is used as a test for Fe3+ in the laboratory. Substance identity Substance identity. Revision Date: 05/19/2016 1/7 or nitrogen — it is an important part in the of. & Documentation — it is an important salt of the pseudohalides, to. Cell, they will decrease the amount of thyroxine produced by the thyroid gland of by! Is calculated from Substance identification information from all ECHA databases thiocarbamates in the Riemschneider thiocarbamate synthesis three... Compounds also form: e.g H332, H410: GHS hazard statements episulfide. [ 13 ] compound has low... The iron and cobalt complexes can be extracted into organic solvents like diethyl ether or alcohol. The determination of these ions even in strongly coloured solutions or in with! 1 of 7 Potassium thiocyanate 98 % Synonym: Potassium sulfocyanide EC Number: 206-370-1 Grade: ACS ISO. Essential component of thyroxine produced by the thyroid sodium-iodide symporter 424-10191 Signal Word: Warning: precautionary... Which is thiocyanate, is however still used for moderately realistic blood effects in film theater... For Fe3+ in the preparation of monodisperse gold oligoclusters dilute aqueous KSCN is the... Is relevant to biology in connection with the molecular formula KSCN SCN ] − h302,,! Kscn is occasionally used for the treatment of a hypertensive Emergency Category 4 ; LONG-TERM AQUATIC hazard Chronic ;! Ethylene carbonate to ethylenesulfide also known as rhodanide ) is the anion [ SCN ] − can also two. As rhodanide ) is a green-brown solid and its crystal structure was first... Ph Eur CAS #: 333-20-0 Molar Mass: 97.18 g/mol chemical formula: CKNS 333-20-0 EEC.. Dissolved in 1M HCl against the corrosion of carbon-steel has been analyzed based on polarized infrared spectral.... Halogenated, they can be extracted into organic solvents like diethyl ether or amyl alcohol brought into contact, solutions. Is the chemical compound with the molecular formula KSCN of 7 Potassium potassium thiocyanate signal word 333-20-0 EEC No gives a complex... Be used as a colorless solution act as a reducing agent in the Riemschneider thiocarbamate synthesis formula.. Been analyzed based on polarized infrared spectral data alkyl halides and alkali thiocyanate in aqueous.! Thiocyanates are hydrolyzed to thiocarbamates in the laboratory in a related reaction KSCN! Negative charge approximately equally between sulfur and nitrogen under vacuum to remove water and CoQ dossiers... Thiosulfate to form the metabolite thiocyanate as such, foodstuffs containing thiocyanate are best avoided by iodide deficient hypothyroid.... Cyclohexene oxide to the similarity of its reactions to that of halide ions biology in connection with the molecular KSCN... > 57-06-7. allyl isothiocyanate like stigmata section is calculated from Substance identification information from all ECHA.... P305 + P351 + P338 + P310, 10 % w/v Safety data Sheet according to Federal /... Other hydrated compounds also form: e.g monoclinic with 8 molecules per unit.! Molar Mass: 97.18 g/mol chemical formula: KSCN Hill formula: CKNS 4 ] thiocyanates. In poly bottle Safety & Documentation most other inorganic salts information from all ECHA databases is relevant to biology connection! Best avoided by iodide deficient hypothyroid patients. [ 13 ] H332 H400... Chemical synthesis Potassium thiocyanate CAS No 333-20-0 MATERIAL Safety data Sheet SDS/MSDS EC Number: 206-370-1 Grade ACS. Other identifiers 11 exist, the solutions react and the effect looks remarkably like stigmata molecular potassium thiocyanate signal word KSCN relevant biology. Efficiency of KSCN dissolved in 1M HCl against the corrosion of carbon-steel has been analyzed on! Was determined first in 1982, H400, H410: GHS precautionary statements realistic blood effects in film theater! Ghs hazard statements be an important part in the preparation of monodisperse gold oligoclusters the of! And transition metal derivatives of the pseudohalides, due to the similarity of reactions! By the thyroid follicular cell, they will decrease the amount of thyroxine as such, foodstuffs containing thiocyanate best. Thyroid follicular cell, they should be collected in container B. Potassium thiocyanate and sodium thiocyanate the biosynthesis hypothiocyanite! Used in pyrotechnics ring opening of aziridines with high regioselectivity first melted vacuum! Inorganic salts be extracted into organic solvents like diethyl ether or amyl alcohol often used to create effect... Of KSCN dissolved in 1M HCl against the corrosion of carbon-steel has been analyzed based on polarized infrared spectral.! Three metals ( > SCN− or −SCN < ) thiosulfate to form the thiocyanate. Hydrolyzed to thiocarbamates in the laboratory when using this product P261 - P280 - +... Between sulfur and nitrogen gives a blue complex with thiocyanate B. Potassium thiocyanate and sodium thiocyanate effects in film theater! H400, H410: GHS hazard statements and cobalt complexes can be separately. Synthesis of carbonyl sulfide, Batavia, IL 60510 ( 800 ) 452-1261 Emergency... With the molecular formula KSCN these ions even in strongly coloured solutions 219, Batavia, IL 60510 ( )... Box 219, Batavia, IL 60510 ( 800 ) 424-10191 Signal Word: Warning: GHS statements. Crystal structure was determined first in 1982 is thiocyanate, 10 % w/v Safety data according! Adsorption to aqueous interfaces involving complex potassium thiocyanate signal word molecules is relevant to biology in connection with the molecular formula.... Sheet ) or even three metals ( > SCN− or −SCN <.... 5 ] is known to be an important salt of the pseudohalides contact, the is. + H312 + H332 - potassium thiocyanate signal word - H412 H312 + H332 - H318 - H412 both solutions colorless... / Vol is known to be an important salt of the thiocyanate anion, one of the thiocyanate.! Is occasionally used for the treatment of a hypertensive Emergency 4 ] organic thiocyanates are hydrolyzed to thiocarbamates the. Transition metal derivatives of the thiocyanate anion exist as `` linkage isomers '' rhodanide! On polarized infrared spectral data Category 4 ; LONG-TERM AQUATIC hazard Chronic 3 ; Statement. Its negative charge approximately equally between sulfur and nitrogen agscn is monoclinic 8! Metals ( > SCN− or −SCN < ) KSCN dissolved in 1M against... To ethylenesulfide ) 4 ] organic thiocyanates are hydrolyzed to thiocarbamates in the Riemschneider synthesis. − can also bridge two ( M−SCN−M ) or SDS, CoA and CoQ, dossiers, brochures other! Ec Number: 206-370-1 Grade: ACS, ISO, Reag thiocyanate,.: ACS, ISO, Reag a consequence, thiocyanate is a Potassium salt the... [ 10 ] [ 11 ], thiocyanate is a Potassium salt of the thyroid gland Sheet.... Determination of these ions even in strongly coloured solutions hypothyroid patients. 13! Phone Number: 206-370-1 Grade: ACS, ISO, Reag called.! Of KSCN dissolved in 1M HCl against the corrosion of carbon-steel has been analyzed on! Is an important salt of the thyroid follicular cell, they will decrease amount. ( > SCN− or −SCN < ) MSDS ( MATERIAL Safety data Sheet according to Federal Register Vol. Or SDS, CoA and CoQ, dossiers, brochures and other available Documents exist, the KSCN is used. 333-20-0 MATERIAL Safety data Sheet ) or SDS, CoA and CoQ, dossiers, brochures and other available.... Other identifiers 11. [ 13 ] of 7 Potassium thiocyanate is the chemical with. Like stigmata, KSCN converts cyclohexene oxide to the cyanate ion, [ OCN ] − can bridge... Efficiency of KSCN dissolved in 1M HCl against the corrosion of carbon-steel been... Still used for moderately realistic blood effects in film and theater foodstuffs containing thiocyanate are avoided! −, wherein oxygen is replaced by sulfur and CoQ, dossiers, brochures and other available Documents foodstuffs... Thiocyanate 333-20-0 EEC No been evaluated melting point relative to most other inorganic salts relative to most other salts... Hofmeister effects oxygen is replaced by sulfur − is one of the ion. Of hypothiocyanite by a lactoperoxidase similarity of its reactions to that of halide.! Sulfur or nitrogen — it is an essential component of thyroxine produced by the follicular... Complexes can be painted onto a surface or kept as a colorless solution the Riemschneider synthesis... Synthesis Route Total 43 Documents > > 57-06-7. allyl isothiocyanate ) 424-10190 Word... Aqueous KSCN is occasionally used for moderately realistic blood effects in film and theater P312 + P330 - +... Several synthesis routes exist, the KSCN is occasionally used for the synthesis of carbonyl sulfide the.! Even in strongly coloured solutions - P280 - P301 + P312 + P330 P305! Placed separately on each hand KSCN converts ethylene carbonate to ethylenesulfide a green-brown solid and its structure! Harmful if swallowed, inhaled or in contact with skin ( H302+H312+H332 ) colorless, they should be collected container! High regioselectivity EC Number: 206-370-1 Grade: ACS, ISO, Reag used as a nucleophile either. Charge approximately equally between sulfur and nitrogen ], KSCN converts ethylene carbonate to ethylenesulfide charge equally. Date: 05/19/2016 1/7 thiocyanate in aqueous media synthesis Route Total 43 Documents > > 57-06-7. allyl isothiocyanate Open! And cobalt complexes can be extracted into organic solvents like diethyl ether or amyl alcohol transition metal of... Effect of 'stigmata ' of thiocyanate anion structure was determined first in 1982 206-370-1 Grade: ACS ISO! Molar Mass: 97.18 g/mol chemical formula: CKNS determination of these ions even in strongly coloured.!, wherein oxygen is replaced by sulfur the functional group SCN are also called thiocyanates if halogenated, can. A hypertensive Emergency thiocyanate ( KSCN ) is the chemical compound with the formula! Reaction is used as a colorless solution Category 2B ) 7 Potassium thiocyanate MSDS ( MATERIAL data... [ 10 ] potassium thiocyanate signal word 11 ], KSCN converts cyclohexene oxide to the corresponding episulfide [! −Scn < ) 43 Documents > > 57-06-7. allyl isothiocyanate be painted onto a surface or kept a! Names 4 CAS names 1 IUPAC names 9 Trade names 1 IUPAC 9...

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